Toxic Air Pollutants

1. Definition of Air Toxics
2. Health and Environmental Effects
3. Sources of Air Toxics
4. Exposure to Air Toxics
5. Regulation by the EPA
6. National Air Toxics Assessment of 33 air toxics
7. 3 Examples: carbon tetrachloride, acrolein, butadiene

 

1. Definition of Air Toxics

AKA Hazardous Air Pollutants (HAP's)
Air-borne pollutants that are known or suspected to cause cancer or other serious health effects, such as reproductive effects or birth defects, or to cause adverse environmental effects.

The Clean Air Act identifies 188 air toxics which are regulated by the EPA. Examples include:

Organic compounds such as Formaldehyde, Benzene, Carbon Tetrachloride, Butadiene, Acrolein

Metals such as Chromium, Mercury, Cadmium

 

2. Health and Environmental Effects

Human Health Effects
"It has never been proven that air toxics are hazardous to people"  Tom DeLay
Increased Risk of Cancer
Respiratory Ailments
Neurological Damage
Immune System
Reproductive System, including Birth Defects

Environmental Effects
Contamination of Soils and Surface Waters
Effects on Plants and Animals
Damage to Ecosystems

Effects depend on
Quantity of toxic air polluntant
Duration and frequency of exposure
Toxicity of pollutant
Susceptibility

3. Sources of Air Toxics

Mobile Sources (transportation)
Area Sources (e.g. fertilizer application)
Stationary Sources (chemical plants, oil refineries, power plants, aerospace manufacturers, steel mills, dry cleaners, smelters, chromium electroplating, etc.)

4. Exposure to Air Toxics

Breathing Contaminated Air
Eating Contaminated Food Products
Drinking Contaminated Water
Ingesting Contaminated Soil

5. Regulation by the EPA

Standards for mobile and stationary sources
Based on Maximum Achievable Control Technology
Reduce emissions first - determine risks later

6. National Air Toxics Assessment of 33 air toxics

1. Emissions Inventory
2.
Modeled Ambient Concentrations
3.
Modeled Human Exposure
4. Estimated Risk
a.
Cancer Risk: n in a million lifetime risk
b.
Non-cancer Risk: Hazard Quotient

 

7a. Example: Carbon Tetrachloride

Stable gaseous compound: residence time of 50 years

Sources

1) carbon tetrachloride production;
2) pesticide/grain fumigant usage
3) chlorinated paraffin wax production
4) fluorocarbon production

Risk Map for Colorado

Emissions in Colorado

7b. Example: Butadiene

Colorless gas with mild gasoline odor

 

 

Sources: fuel production, synthetic rubber production, automobile exhaust, agricultural fungicides

Risk Map for Colorado

Emissions in Colorado

7c. Example: Acrolein

Clear or yellow liquid with strong odor
Evaporates easily when heated

Sources:
Burning of trees, tobacco, other plants, gasoline, and oil
Pesticide
Chemical manufacturing

Breaks down rapidly - exposure near source
Contaminates soils, water
Respiratory effects (not a known carcinogen)

Risk Map for Colorado

Emissions in Colorado